Nomenclature of Organic Chemistry

spoken language of Organic ChemistryOrganic lyricOxford Dictionaries (n.d.) defines spoken language as the devising or choosing of put ups for things, especially in a science or other disciplineDictionaries, emailprotectedauthor-year.I believe the easiest counsel to understand the rules associated with the IUPAC nomenclature of complete chemistry is with examples and so the majority of this leaven will be dealing with examples and their explanations.Simek (1999) introduces the systematic appointment of an organic chemical compound with a fundamental rule, that to begin naming, wiz mustiness first happen upon the p arnt construction, based on naming a hints longest filament of coulombs connected by single bonds, whether in a continuous kitchen range or in a ring. afterward which, all deviations, either treble bonds or atoms other than carbon and heat content, be indicated by prefixes or suffixes according to a specific set of priorities.Simek (1999) also describes how paraffin waxs argon saturated hydrocarbons, which ar particles only containing carbon and hydrogen bonded by single bonds only. Alkanes can be subdivided into two main hosts, linear and cyclical linear describes grains that can be bonded in continuous custody and cyclic describes grains that atomic number 18 bonded in a ring care structure.The simplest of all to get to are straight chain alkanesCH4MethaneC2H6ethaneC3H8Propane C4H10ButaneC5H12PentaneC6H14HexaneC7H16HeptaneC8H18OctaneC9H20NonaneC10H22DecaneC11H24UndecaneC12H26Dodecane In order to do cycloalkanes, the prefix cyclo is calldC3H6CyclopropaneC4H8CyclobutaneC5H10CycloheptaneNomenclature of Branched Chain AlkanesUniversity of California, Davis (n.d.) describes how An alkyl pigeonholing group is organise by removing one hydrogen from the alkane chain, and is described by the prescript CnH2n+1. The removal of this hydrogen results in a stem change from-aneto-yl. E.g. Propane to propyl.In order to systemati cally name a molecule, first determine the refer structure. In this case the longest carbon chain is 6-Carbons long, as a result the put forward structure is Hexane.The carbons in the chain are numbered from the closing braggart(a) the substituents (The group substituted in place of hydrogen, in this case the substituent is CH3-Methyl) the last-place accomplishable numberThe substituents or functional groups that are attached to the parent chain are then named. There are two, one-carbon long alkyl groups and as a result take methane, drop the -ane and replace it with yl, giving methyl.N.B. If the alkyl group is two-carbons long (CH3CH2), the name would be ethyl, CH3CH2CH2- propyl, CH3CH2CH2CH2- butyl.Number the substituents to identify their prospects relative to the parent structure.Here, substituent positions are 2 and 4.Hardinger (2008) emphasises that a number must be assigned to each substituent, along with its prefix (di-, tri-, terta-, penta-, etc.), even if the said (prenominal) substituents are present in the molecule In this example 2,4-dimethyl. fructify numbers game for substituents are ordered numerically, substituent names are ordered alphabetically (prefixes such as di-, tri-, tetra-, etc., are excluded from alphabetical ordering, but cyclo, iso and neo are include) and are then indite before the parent name.If these rules are adhered to, the molecule is named as 2,4-dimethylhexane.Nomenclature of AlkenesAlkenes are unsaturated hydrocarbons and differ from alkanes, as they founder at least one C=C double bond. Alkenes confine the general polity CnH2n, which is the aforesaid(prenominal) general formula for cycloalkanes.Following the same basic rules as before, identify the parent structure. Here, the longest carbon chain is 7-Carbons long, thus the parent structure is heptane.The molecule is numbered so that the substituents switch the lowest possible position numbers.The substituents are then named. As the molecule has a double bond, it is set as an alkene and as the parent structure is heptane, it is named heptene. However, take into account there is also a methyl group. add up the positions of the substituents gives, 2-methyl and 1,3-diene, since the molecule contains one methyl group and two double bonds. target numbers are ordered numerically, the substituents ordered alphabetically and both compose before the parent name. Due to the fact the double bonds drill a suffix (-ene is at the culmination of the name), 1,3-diene is not ordered before 2-methyl.consistently naming the molecule gives it an IUPAC name of 2-methylhepta-1,3-diene.Nomenclature of HaloalkanesHaloalkanes are organic compounds, where an alkane contains at least one halogen. Haloalkanes cede a general formula of CnH2n+1X (X=Halogen e.g. Cl)In order to name haloalkanes, the ine of the halogen name is removed, leaving the prefix (e.g. degree Fahrenheit becomes floro-, chlorine becomes chloro-, etc.). The same rules are then applied t o systematically name the haloalkane.Nomenclature of AlkynesAlkynes are unsaturated hydrocarbons, as they contain at least one CC bond. Alkynes have the general formula CnH2n-2. over again identify the parent structure, the longest carbon chain is 7-Carbons long and so the parent structure is identified as heptane.The molecule is numbered so substituent positions have the lowest possible numbers.Here the substituents are two methyl groups, one chloro group and one CC triple bond. The longest chain is 7-Carbons long and contains a CC triple bond indeed, it is identified as heptyne.The substituent positions are numbered giving 6,6-dimethyl, 4-chloro and hept-2-yne.Finally position numbers are ordered numerically, substituent names are ordered alphabetically and are written in front of the parent name.The molecule is given an IUPAC name 4-chloro-6,6-dimethylhept-2-yne.Nomenclature of AlcoholsAlcohols are organic compounds containing at least one OH group bonded to it. The hydroxyl group replaces a hydrogen on a carbon and beca habituate of this, alcohols have the general formula CnH2n+1OH.The parent structure for this molecule is identified as octane, since the longest carbon chain is 8-Carbons long.The molecule is numbered, giving the lowest possible numbers to substituents.Substituents in this molecule are one hydroxyl group and one chloro group. The longest carbon chain is 8-Carbons long and since it contains a hydroxyl group, it is identified as an alcohol.The position numbers for substituents are 4-chloro and octan-2-ol.Position numbers are ordered numerically, substituent names are ordered alphabetically and are placed before the parent name (the hydroxyl group identifies the molecule as an alcohol, as such, it uses the suffix ol instead of the prefix hydroxy-).The molecule has an IUPAC name 4-chlorooctan-2-ol.Nomenclature of AminesAmines are derivatives of ammonia (NH3), the replacing of one or more than hydrogens in ammonia with organic compound(s) realizes an amine. Replacing one hydrogen, will create a primary amine, two hydrogens secondary amine, three hydrogens tertiary amine.Methylamine (primary) Dimethylamine (secondary) Trimethylamine (tertiary)When naming amines, the longest carbon chain including the amine group is determined and numbered so to give the amine group the lowest possible position number.If the molecule is a secondary amine, the longest carbon chain is utilise as the parent structure and the other chain is denoted with N-alkyl (if both chains are of equal length, the molecule can be named dialkylamine).If the molecule is a tertiary amine, like secondary amines the longest carbon chain is used as the parent structure and the other chains are denoted with N-alkyl (if all chains are of equal length, the molecule can be named trialkylamine).Nomenclature of EthersUniversity of California, Davis (n.d.) describes ethers as, organic compounds that contain two alkyl groups bonded to an oxygen atom (e.g. CH3CH2 OCH3).Ethers only use the prefix alkoxy-, where the ane of the alkane is removed. According to University of California, Davis (n.d.) the prefix alkoxy- is always treated as a substituent, because there is no suffix for ethers.When naming the molecule the shorter carbon chain becomes the alkoxy- substituent (e.g. methoxy) and the longer carbon chain is identified as the parent structure.Nomenclature of Aldehydes and KetonesBoth aldehydes and ketones are organic compounds that contain the carbonyl group C=O. Aldehydes feature at the end of a carbon chain (e.g. CH3CH2CH2CHO), whereas, ketones are part of the carbon chain (e.g. CH3CH2COCH3)When naming aldehydes it is chief(prenominal) to note that they exist only on the ends of carbon chains and therefore do not need a position number included in the name, the aldehyde is presumed to be position 1. Aldehydes use the suffix al in naming and replace the e at the end of alkanes (e.g. Butane becomes butanal).Ketones use the suffix one i n naming and replace the e at the end of alkanes (e.g. pentane becomes pentanone) however, unlike aldehydes ketones need position numbers, as there are multiple positions for the C=O bond (with the exception of simple ketones like propanone, as there is only one position for the carbonyl group).Nomenclature of carboxyl AcidsCarboxylic irates are organic compounds that contain the carboxyl group COOH. Like aldehydes carboxyl acids are only present at the end of carbon chains and therefore, do not have positions numbers. Carboxylic acids use the suffix oic acid and replace the e at the end of alkanes (e.g. Ethane becomes ethanoic acid).N.B. One must be aware, that although there are systematic IUPAC names for all molecules, some molecules have common names e.g. ethanoic acid used to be known as acetic acid and is most usually known as vinegar.Nomenclature of EstersEsters are formed from reacting a carboxylic acids with alcohols.University of California, Davis (n.d.) briefly explains , that esters are named by treating the alkyl chain from the alcohol as a substituent and the carboxylic acid forms the parent structure, where the oic acid part is replaced with oate (e.g. Ethanoic acid becomes ethanoate).Nomenclature of Aromatic CompoundsSimek (1999) describes, how aromatic compounds are derived from benzene rings (C6H6), by replacing one hydrogen with a substituent group. The removal of one hydrogen from the benzene results in the phenyl group.When naming aromatic compounds the parent name benzene is used and appropriate prefixes.Priority Rules of NomenclatureWhen the molecule being named has multiple functional groups and substituent groups, the group with highest priority is numbered so it has the lowest possible position number.This list based on Simeks (1999) priority table, shows priorities from highest to lowestCarboxylic AcidsEstersAldehydesKetonesAlcoholsAminesAlkenesAlkynesAlkylsEthersHalo CompoundsAromatic CompoundsReferencesSimek, J., 1999.IUPAC_Handou t. e-book San Luis Obispo California Polytechnic State University. Available at http//www.angelo.edu/faculty/kboudrea/organic/IUPAC_Handout.pdf Accessed 10 Feb. 14Lam, D., n.d. online Nomenclature of Benzenes Chemwiki. Available at http//chemwiki.ucdavis.edu/Organic_Chemistry/Hydrocarbons/Aromatics/Nomenclature_of_Benzenes Accessed 13 Feb. 14Oxford Dictionaries. N.d. onlinenomenclature definition of nomenclature in Oxford dictionary (British World English). Available at http//www.oxforddictionaries.com/definition/english/nomenclature Accessed 10 Feb. 14Hardinger, S., 2008. Nomenclature_02. e-book Los Angeles University of California. Available at http//www.chem.ucla.edu/harding/notes/nomenclature_02.pdf Accessed 10 Feb. 14Clark, J. 2000. online Naming aromatic compounds. Available at http//www.chemguide.co.uk/basicorg/conventions/names3.html Accessed 12 Feb. 14